Enantioselective Allylation of Aldehydes Catalyzed by Diastereoisomeric Bis(tetrahydroisoquinoline) N,N'-Dioxides

Abstract

Enantioselective allylation of aromatic and ,-unsaturated aldehydes with allyltrichlorosilane catalyzed by two diastereoisomeric (R,Rax,R)- and (R,Sax,R)-bis-1,1-[5,6,7,8-tetrahydro- 3-(tetrahydrofuran-2-yl)isoquinoline] N,N-dioxides was studied.

Keywords

• Enantioselective
• Allylation
• Aldehydes
• Catalyzed
• Diastereoisomeric
• Bis(tetrahydroisoquinoline)
• N
• N’-Dioxides