Lewis Base-Catalyzed Enantioselective Allylation of alpha,beta-Unsaturated Aldehydes.

Abstract

Catalytic allylation of alpha,beta-unsaturated aldehydes with allyltrichlorosilane in the presence of chiral 3,3'-unsymmetrically substituted bis(tetra-hydroisoquinoline) N,N-dioxides was explored.

Keywords

• Lewis
• Base-Catalyzed
• Enantioselective
• Allylation
• alpha
• beta-Unsaturated
• Aldehydes.