Structure, Properties and Comparison of C,N-chelated and Amidostabilized Plumbylenes

Abstract

The molecular structure of {2-[(CH3)(2)NCH2]C6H4}(2)Pb (1) in the solid state was determined by X-ray diffraction techniques on a single crystalline material. Bulky amido ligand stabilized complexes [(i-C3H7)(2)C6H3]NHLi (2) and [(i-C3H7)(2)C6H3N(Me3Si)](2)Pb (3) were synthesized and characterized both in the solid state and solution by H-1, C-13, N-15 and Pb-207 NMR and XRD techniques.

The structure of both C,N-chelated and bulky amido plumbylenes is compared.

Keywords

• Lead
• Bulky amides
• C
• N-chelates
• Plumbylenes
• Organoelement chemistry
• X-ray diffraction