Palladium(II) aryl-amido complexes of diphosphinoazines in unsymmetrical PNP' pincer-type configuration

Abstract

Square planar palladium(II) aryl-amido complexes of diphosphinoazines in monoanionic unsymmetrical PNP' pincer-type coordination were prepared by reactions of phenyl-, o-tolyl-, or 2,6-dimethylphenyllithium with previously described chloro-amido complex

Keywords

• diphosphinoazines
• pincer complexes
• aryl-amido complexes
• palladium
• polydentate ligands
• h oxidative addition
• reductive elimination
• crystal-structures
• phosphine-ligands
• n-c
• activation
• coordination
• platinum
• rhodium
• bonds