REACTIONS OF DOUBLY TUCKED-IN PERMETHYLTITANOCENE WITH tert-BUTANOL AND PROPARGYL ALCOHOL. THE CRYSTAL STRUCTURES OF UNUSUAL HYDROLYTIC BYPRODUCTS

Abstract

Reactions of double tucked-in permethyltitanocene [Ti{eta(3):eta(4)-C5Me3(CH2)(2)}(eta(5)-C5Me5)] (1) with tert-butanol or propargyl alcohol in toluene proceeded sluggishly even with excess of the alcohol and at elevated temperature. The alcoholysis of 1

Keywords

• Titanium
• Double tucked-in titanocene
• Allyl-diene ligand
• Alcoholysis
• tert-Butanol
• Propargyl alcohol
• NMR spectra
• Hydrolysis byproduct
• Crystal structures
• x-ray-structure
• molecular-structure
• complexes
• reactivity
• ligands
• ti
• titanocene
• alkoxide