Enantiomerically pure axially chiral aminocarbene complexes of chromium

Abstract

Aminocarbene complexes having a methyl group in the ortho-position to the aminocarbene moiety on the aromatic ring, (S)-pentacarbonyl[(NN-dimethylamino)(3-methoxycarbonyt-2-methylphenyl)carbene]chromium(0) [(S)-6] and (R)-pentacarbonyl[(NN-dimethylamino)

Keywords

• fischer carbene complexes
• (aminocarbene)chromium(0) complexes
• alkene complex
• carbon
• ring