The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents

Abstract

The organoantimony(III) difluorides containing Y,C,Y-chelating, so called pincer, ligands ([2,6-(YCH2)(2)C6H3]SbF2; Y=MeO, t-BuO and Me2N) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)(2)C6H3]SbCl2; Y=MeO, t-BuO and Me2N) with t

Keywords

• antimony
• fluorine
• tin
• chelating ligand
• X-ray structure
• ray structure-analysis
• organometallic fluorides
• tetraarylbismuthonium salts
• intramolecular coordination
• crystal-structures
• halides
• derivatives
• behavior
• bearing
• 10-sb-5