New complexes of molybdenum(II) and tungsten(II) with a C,N-chelated stannylene

Abstract

Two new complexes of [Sn{2-[(CH3)(2)NCH2]C6H4}(2)] with [Mo(eta(5)-C5H5)(CO)(3)Cl] and [W(eta(5)- C5H5)(CO)(3)Cl], respectively, were prepared via insertion of stannylene into the Mo - Cl or W - Cl bond forming thus the transition metal - tin bond.

Keywords

• stannylene
• C
• N-ligand
• molybdenum
• tungsten
• X-ray diffraction
• stannanes
• organotin compounds
• half-sandwich complexes
• 4B METAL ALKYLS
• SN-N
• TIN
• MO
• SPECTROSCOPY
• GERMANIUM
• CRYSTAL
• AMIDES
• LIGAND
• CR