Synthesis and structural study of organoantimony(III) and organobismuth(III) triflates and cations containing O,C,O-pincer type ligands

Abstract

The reactions of intramolecularly coordinated organoantimony and organobismuth dihalides (LSbCl2)-Sb-1 and (LBiCl2)-Bi-2, containing two types of O,C,O-pincer ligands 2,6-(ROCH2)C6H3- (L-1, R = Me; L-2, R = Bu-t), with silver salts of the weakly nucleoph

Keywords

• ray crystal-structures
• rare-earth-metals
• olefin polymerization
• o
• c
• o-chelating ligands
• carborane anion
• lone-pair
• complexes
• catalysts
• chemistry
• bismuth(iii)