Capillary electrophoretic separation and kinetic study of inert copper(II) complexes of 1,8-bis(methylphosphonate) derivative of cyclam

Abstract

Isomerisation of the pentacoordinated isomer of the copper(II) complex of 1,8-bis(phosphonic acid) derivative of cyclam to the hexacoordinated one was evaluated by means of electrophoresis.

Keywords

• capillary electrophoresis
• kinetics
• 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid)
• copper complexes
• isomerization
• phosphonate complexes