Thermodynamic, kinetic and solid-state study of divalent metal complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam) bearing two trans (1,8-)methylphosphonic acid pendant arms

Abstract

Thermodynamic and kinetic properties of divalent metal complexes of 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) were investigated. Solid-state structures of manganese(II), zinc(II) and lead(II) complexes determined.

Keywords

• Cambridge Structural Database
• crystal-structures
• macrocyclic ligands
• copper(II) complexes
• lead(II) diphosphonates
• hydrothermal syntheses
• dissociation kinetics
• lanthanide complexes
• cis/trans-isomerism
• aqueous-solutions