Structure and solution study of molecular triorganotin compounds containing an N,C,N ligand

Abstract

The triorganotin compounds R-2(NCN)SnX (NCN = C6H3(Me2NCH2)(2-)2,6(-)) containing different polar groups X or substituents R were prepared. The set of organotin compounds Ph-2(NCN)SnX (X = 1 (2), CF3CO2 (3), CH3CO2 (4), Et2NCS2 (5)) was prepared to study

Keywords

• stabilized silyl cations
• pincer-type ligand
• intramolecular coordination
• organotin compounds
• crystal-structure
• o
• c
• o-chelating ligands
• sn-n
• pentacoordinate
• complexes
• cyclization