Synthesis of Phenylacetylene and 3-Thienylacetylene with Heterogenized Rh Catalysts

Abstract

Phenylacetylene and 3-ethynylthiophene was polymerized with heterogenized catalysts prepared by immobilization of Rh(cyclodiene) complexes on inorganic and organic supports of various chemical composition and architecture of pores.

Keywords

• Rh(I) complexes
• mesoporous molecular sieves
• acetylenes polymerization
• polyacetylenes
• ethynylthiophene
• heterogenized catalysts