Analyte and system eigenpeaks in nonaqueous capillary zone electrophoresis: Theoretical description and experimental confirmation with methanol as solvent

Abstract

A mathematical model developed for aqueous solutions and adapted to methanol as solvent was applied to predict the electromigration characteristics of analytes and background electrolytes in CZE.

Keywords

• background electrolyte
• capillary zone electrophoresis
• eigenpeaks
• methanol
• system peaks
• organic solvents
• peak shape
• eigenmobilities
• optimization
• eletromigration
• separations