Synthesis and Characterization of Dinuclear Rh(diene) Complexes with Aryloxo Bridge Ligands and their Catalytic Activity in Hydroformylation, ATRP and Polymerization of Substituted Acetylenes.

Abstract

Dinuclear Rh-diene complexes with aryloxo bridge ligands were synthetised, characterized and tested as catalysts in hydroformylation and polymerization reactions.

Keywords

• Rh-complexes
• catalytic activity
• hydroformylation
• ATRP
• insertion polymerization
• homogeneous catalysis