Palladium(II) amido complexes with an unsymmetrical PNP ' pincer-type coordination and a new (E,-E)-tetradentate diphosphinoazine coordination mode

Abstract

New palladium(II) complexes of diphosphinoazines were synthesized. The previously unknown (E,E)-tetradentate coordination mode of diphosphinoazine was observed using X-ray structure determinaton.

Keywords

• axial chirality
• amido complexes
• palladium
• diphosphinoazine
• P-N ligand