Aziridine Ring Cleavage by Nucleophiles in Epimino Derivatives of 1,6-Anhydro-beta-D-hexopyranoses

Abstrakt

The regioselectivity of aziridine ring cleavage by nucleophiles in a series of N-tosyl- and N-benzylepiminoderivatives of 1,6-anhydro-β-D-hexopyranoses of D-allo, D-manno and D-galacto configurations has been studied.

Klíčová slova

• azides
• carbohydrates
• cleavage reactions
• epimines
• NMR spectroscopy