Co-ordination Polymerization of Phenylacetylen and Atom Transfer Radical Polymerization of Vinyl Monomers Induced by Oxalamidinato Rh-Complexes

Abstract

Dinuclear Rh-complexes [(T1T2)Rh(oxam)Rh(T2T1)] with N-substituted axalamidoinato bridges and various terminal ligands were tested as catalysts of co-ordination polymerization of PhA and ATRP