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Amorphous 5f Ferromagnetic Hydrides UH3Mox

Publication at Faculty of Mathematics and Physics |
2014

Abstract

gamma-U metal, stabilized down to room temperature in the bcc structure by Mo doping, can absorb hydrogen at high H-2 pressures only. The product is amorphous hydride UH3Mox analogous to beta-UH3.

Such hydrides are ferromagnetic with high Curie temperatures (up to 200 K), enhanced with respect to beta-UH3. Magnetic moment of U also increases.

Large disorder together with high anisotropy lead to a very high coercivity, reaching 4 T at low temperatures. As amorphization normally tends to suppress magnetic ordering of U compounds, such hydrides represent a new class of materials, amorphous U-based ferromagnets with relatively high Curie temperature.