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Reaction of NH2+ with H2 in the rf Ion Trap Between 100 K and 300 K

Publication at Faculty of Mathematics and Physics |
2016

Abstract

The interaction of NH2+ with H2 has been studied experimentally in temperature range 100-300 K using a cryogenic rf 22-pole trap. The reaction rate coefficient decreases slowly from 4.8x10MINUS SIGN 10 cm3 s MINUS SIGN 1 at 97 K to 1.9x10MINUS SIGN 10 cm3 s MINUS SIGN 1 at 300 K.

The measured data are within 25 % overall uncertainty in a good agreement with obtained earlier results at 300 K in selected ion flow tube experiment and ion cyclotron resonance experiment.