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Superconducting phase transitions in the milikelvin temperature range in splat-cooled U-Pt alloys

Publication at Faculty of Mathematics and Physics |
2017

Abstract

We present the temperature and magnetic-field dependence of electrical resistivity (ρ(T, B) dependence) in the milikelvin range for U-Pt alloys with Pt concentration in the range of 0-15 atomic percent (at.%) prepared by splat-cooling technique. The high-temperature cubic γ-U phase can be stabilized down to room temperature in the samples with 15 at.% Pt.

All samples exhibit superconducting transitions below 1.1K revealed by abrupt resistivity drops with transition widths of several tens of milikelvins in zero magnetic field. The H-T diagrams for all investigated alloys are in good agreement with the Ginzburg-Landau approximation.

The U-Pt alloys with cubic γ-U phase are very stable in air and hydrogen exposure at atmospheric conditions. They can absorb a large amount of hydrogen upon applying hydrogen pressure >2.5 bars and easily release it by heating in vacuum, showing the possibility of using U-Pt-based hydrides as a medium for hydrogen storage.