Abstract
The present paper reports a one-pot synthesis of magnetic nanocomposites samples through acid catalyzed sol-gel method. Fe(III) acetylacetonate was used as precursor of the iron oxide phase: tetraethylortosilicate for the silica phase and polyvinyl alcohol (PVA, molecular mass 49000) as pore former.
Different concentrations of Fe2O3 in composites matrices were prepared and studied ranging from 0% to 20%. All reactions took place in one pot at room temperature; the materials were subsequently heat treated at 300 degrees C, to ensure the crystallinity for the iron oxide having spinel structure, forming nanoparticles confined in the silica matrix.
The materials were characterized using X-ray diffraction, small-angle neutron scattering, FT-IR spectroscopy, nitrogen adsorption, Mossbauer spectroscopy and magnetization measurements. The maximum value of room temperature saturation magnetization of approximate to 54 emu/g and 0.11 kOe coercive field was achieved for the magnetic nanocomposite sample with 20% Fe2O3.
The highest surface area of 680m(2)/g was obtained for the sample with 10% Fe2O3. The potential applicability of the obtained materials was studied for adsorption performance for cadmium in aqueous solutions.
The Langmuir isotherm model described well the adsorption data, indicating monolayer adsorption of Cd(II) on the heterogeneous composite surface.