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BRAUN-LE CHATELIER PRINCIPLE IN DISSIPATIVE THERMODYNAMICS

Publication at Faculty of Mathematics and Physics |
2019

Abstract

Braun-Le Chatelier principle is a fundamental result of equilibrium thermodynamics, showing how stable equilibrium states shift when external conditions are varied. The principle follows from convexity of a thermodynamic potential.

Analogically, from convexity of a dissipation potential it follows how steady non-equilibrium states shift when thermodynamic forces are varied, which is the extension of the principle to dissipative thermodynamics.