Using nutation-frequency-selective pulses to reduce radio-frequency field inhomogeneity in solid-state NMR
Abstrakt
Radio-frequency (rf) field inhomogeneity is a common problem in NMR which leads to non-ideal rotations of spins in parts of the sample. Often, a physical volume restriction of the sample is used to reduce the effects of rf-field inhomogeneity, especially in solid-state NMR where spacers are inserted to reduce the sample volume to the centre of the coil.
We show that band-selective pulses in the spin-lock frame can be used to apply B1-field selective inversions to spins that experience selected parts of the rf-field distribution. Any frequency band-selective pulse can be used for this purpose, but we chose the family of I-BURP pulses (Geen and Freeman, 1991) for the measurements demonstrated here.
As an example, we show that the implementation of such pulses improves homonuclear frequency-switched Lee-Goldburg decoupling in solid-state NMR.