Abstrakt
Aluminium-steel clad composite was manufactured by twin-roll casting. An intermetallic layer of Al5Fe2 and Al13Fe4 formed at the interface upon annealing above 500 °C.
During in-situ annealing in transmission electron microscope, the layer grew towards the steel side of the interface in tongue-like protrusions. A study of furnace-annealed samples revealed, that the bulk growth of the interface phase proceeds towards the aluminium side.
The growth towards steel is a surface effect that takes place simultaneously with the bulk growth towards aluminium. At the beginning of the intermetallic layer formation diffusion of Fe into aluminium prevails, afterwards Al atoms diffuse throught the newly formed intermetallic layer towards steel and the whole interface shifts towards aluminium.
The kinetics of growth of the intermetallic layer follows parabolic law in both cases, indicating that the growth is governed by diffusion.