Abstract
Two-dimensional (2D) van der Waals (vdW) magnetic 3d-transition metal trihalides are a new class of functional materials showing exotic physical properties useful for spintronic and memory storage applications. In this article, we report the synthesis and electromagnetic characterization of single-crystalline vanadium trichloride, VCl3, a novel 2D layered vdW Mott insulator, which has a rhombohedral structure (R3, No. 148) at room temperature.
VCl3 undergoes a structural phase transition at 103 K and a subsequent antiferromagnetic transition at 21.8 K. Combining core levels and valence bands x-ray photoemission spectroscopy (XPS) with first-principles density functional theory (DFT) calculations, we demonstrate the Mott Hubbard insulating nature of VCl3 and the existence of electron small 2D magnetic polarons localized on V atom sites by V-Cl bond relaxation.
The polarons strongly affect the electromagnetic properties of VCl3 promoting the occupation of dispersion-less spin-polarized V-3d a1g states and band inversion with e'g states. Within the polaronic scenario, it is possible to reconcile different experimental evidences on vanadium trihalides, suggesting that also VI3 hosts polarons.
Our results highlight the complex physical behavior of this class of crystals determined by charge trapping, lattice distortions, correlation effects, mixed valence states, and magnetic states.